oxidation of hydrocarbons in the liquid phase. Edited by N.M. Emanuel". Translated by K.R. Dobson and B.J. Hazzard. Translation edited by J.D. Hopton. by Akademiia nauk SSSR. Institut khimicheskoЗђ fiziki

Cover of: oxidation of hydrocarbons in the liquid phase. | Akademiia nauk SSSR. Institut khimicheskoЗђ fiziki

Published by Macmillan in New York .

Written in English

Read online

Subjects:

  • Hydrocarbons,
  • Oxidation

Edition Notes

Book details

SeriesA Pergamon Press Book
ContributionsĖmanuėlʹ, N. M. 1915-
Classifications
LC ClassificationsQD305 H5 A323 1965
The Physical Object
Pagination407p.
Number of Pages407
ID Numbers
Open LibraryOL16673419M

Download oxidation of hydrocarbons in the liquid phase.

The liquid-phase oxidation of some aryl-aliphatic hydrocarbons is also discussed. This book is comprised of 35 chapters and begins with an analysis of the chain processes taking place during the oxidation of hydrocarbons and how to stimulate slow chain branching reactions.

Topics covered include the chain reactions taking place in the. Oxidation of Hydrocarbons in Liquid Phase; by Emanuel, N. M., (Translated By K. Dobson, And B.

Hazzard; and a great selection of related books, art and. The liquid-phase oxidation of some aryl-aliphatic hydrocarbons is also discussed. This book is comprised of 35 chapters and begins with an analysis of the chain processes taking place during the oxidation of hydrocarbons and how to stimulate slow chain branching cturer: Pergamon.

Buy The Oxidation of Hydrocarbons in the Liquid Phase on FREE SHIPPING on qualified orders The Oxidation of Hydrocarbons in the Liquid Phase: N. Emanuel': : Books.

The catalytic oxidation of hydrocarbons with peroxides, especially the epoxidation of olefins, in liquid phase by titanium catalysts is one of the most actively investigated reactions (60). The active species for this epoxidation reaction is usually assumed to be titanium peroxo moieties, derived from four-coordinate titanium and peroxides.

Additional Physical Format: Online version: Ėmanuėlʹ, N.M. (Nikolaĭ Markovich), Liquid-phase oxidation of hydrocarbons. New York, Plenum Press, The liquid phase oxidation of hydrocarbons.

Part II: the free radical character of the heavy metal catalysed oxidation P. George and A. Robertson, Trans. Faraday Soc.,42, The liquid phase oxidation of hydrocarbons.

Part I: the free radical character of the surface catalysed oxidation of tetralin P. George, Trans. Faraday Soc.,42, The 5-h oxidation of n-dodecane at °C by air at 1 atm is reported for experiments in a borosilicate glass reaction chamber equipped with a gas rate of reaction was limited by the rate of oxygen diffusion from the gas phase due to the rapid reaction of dissolved oxygen.

Semicontinuous Studies on the Reaction Mechanism and Kinetics for the Liquid-Phase Oxidation of p-Xylene to Terephthalic Acid. Industrial & Engineering Chemistry Research46 (26), DOI: /ie Vikram Govindan and, A.

Suresh. Modeling Liquid-Phase Cyclohexane Oxidation. Oxidation of Hydrocarbons Oxidation of Ketones Literature References Chapter 8 The Causes of the Difference Between the Composition of Products Formed in the Oxidation of Organic Substances in the Vapour and Liquid Phases Introduction Differences Between Liquid-Phase and Vapour-Phase Oxidation Reactions Oxidation of.

Russell and Williamson [1,2] performed the first experiments on the co-oxidation of. hydrocarbons with ethers. The theory of these reactions is close to that for the reaction.

of free radical copolymerization [3] and was developed by several researchers []. When. one hydrocarbon R1H is oxidized in the liquid phase at a sufficiently high dioxygen. Get this from a library. The oxidation of hydrocarbons in the liquid phase. [N M Ėmanuėlʹ; Institut khimicheskoĭ fiziki (Akademii︠a︡ nauk SSSR)].

: Liquid-Phase Oxidation of Hydrocarbons: Good Good Hardcover, surplus library copy with the usual stampings; reference n umber taped to spine and front board; otherwise in good condition with clea n text, firm Range: $5 - $ The first book to place recent academic developments within the context of real life industrial applications, this is a timely overview of the field of aerobic oxidation reactions in the liquid phase that also illuminates the key challenges that lie ahead.

Book Description. Providing a comprehensive review of reactions of oxidation for different classes of organic compounds and polymers, and biological processes mediated by free radicals, Oxidation and Antioxidants in Organic Chemistry and Biology puts the data and bibliographical information you need into one easy-to-use resource.

Sequence studies in liquid phase hydrocarbon oxidation. Part 4.—Hydroperoxide-alcohol and hydroperoxide-ketone transitions in the oxidation of ethylbenzene É. Danóczy, I.

Nemes and D. Gál For reproduction of material from all other RSC journals and books. Oxidation of hydrocarbons in the liquid phase.

Oxford. New York, Pergamon Press; [distributed in the Western Hemisphere by Macmillan, New York] [©] (OCoLC) Document Type: Book: All Authors / Contributors: N M Ėmanuėlʹ; Institut khimicheskoĭ fiziki (Akademii︠a︡ nauk SSSR). While, in the liquid-phase oxidation of hydrocarbons by CNTs (CNTs synthesised by the thermal catalytic pyrolysis of carbon-containing raw materials (CVD-process)), the CNTs enhance catalytic processes.

In this study the aerobic liquid phase oxidation of cumene and initiated (by azobisisobutyronitrile) at low-temperature ( K) in the presence. The liquid-phase oxidation of toluene by air is an environmentally benign process to produce benzoic acid and benzaldehyde.

In a bubble column (diameter of 48 mm) reactor, the kinetics of the oxidation reaction was investigated under conditions similar to those of commercial operations. Based on the compositional analysis results of the oxidation products and the. Insight into the free-radical chain mechanism of gold-catalyzed hydrocarbon oxidation reactions in the liquid phase.

Catalysis Today(), DOI: /   Providing a comprehensive review of reactions of oxidation for different classes of organic compounds and polymers, and biological processes mediated by free radicals, Oxidation and Antioxidants in Organic Chemistry and Biology puts the data and bibliographical information you need into one easy-to-use resource.

@article{osti_, title = {Practical aspects of high-temperature oxidation of hydrocarbons in the liquid phase in the presence of acetic or boric anhydrides}, author = {Grozhan, M.M. and Geguchadze, G.R. and Eremeev, A.P. and Kruglov, A.I. and Lebedeva, G.P. and Fedorova, M.N.}, abstractNote = {The authors have noted that the oxidation of aromatic hydrocarbons.

b Gas-Liquid Reactor Model for the Liquid-Phase Oxidation of Hydrocarbons Radmila Jevtic, P. Ramachandran, and M. Dudukovic. Chemical Engineering, Washington University in St. Louis, One Brookings Drive, Campus BoxSt. Louis, MO   Liquid-phase oxidation of hydrocarbons: by Nikolai Markovich Emanuel, Evgenii Timofeevich Denisov [and] Zinaida Kushelevna Maizus.

Translated from the Russian by B.J. Hazzard. With a foreword by Adalbert Farkas. A process for the production of an initiator for the oxidation of hydrocarbons comprises oxidation of a hydrocarbon in the liquid phase by means of an oxygen containing gas in the presence of a metal salt and oxidation of the hydrocarbon in the liquid phase by means of an oxygen containing gas in the presence of a partial quantity of the initial oxidation product from.

The liquid‐phase catalytic oxidation of MX to MPA in acetic acid media is a typical aromatic hydrocarbon oxidation process, which belongs to the kind of. Amorphous Porous Chromium‐Zirconium Bimetallic Phosphate: Synthesis, Characterization and Application in Liquid Phase Oxidation of Hydrocarbons by Different Oxygen Sources.

Lei Sun. College of Chemistry and Molecular Engineering, Nanjing Tech. Liquid phase hydrocarbon oxidation is one of the principal routes towards industrial organic chemicals.

However, low product selectivity and associated by-product formation are major problems in several oxidation processes. As a result of the increasingly stringent environmental regulations, the development of oxidation catalysts has been a major challenge in the last.

Ruthenium (II) complexes are effective catalysts for the deep oxidation of a variety of chlorinated hydrocarbons at ambient temperature and in the liquid phase. Factors such as solvent, substrate, oxidant and concentration affect the reactions.

Liquid-Phase and Solventless Oxidation of Cyclohexane, Benzene, and Other Hydrocarbons by Cerium(IV) Catalyzed by Iridium(III) in Acidic Medium.

Synthetic Communications: Vol. 38, No. 18, pp. The direct electrochemical oxidation of dry hydrocarbon fuels to generate electrical power has the potential to accelerate substantially the use of fuel cells in transportation and distributed.

The Oxidation of Cyclohexane focuses on the processes, methodologies, reactions, and approaches involved in the oxidation of cyclohexane.

The publication first offers information on the theory of slow chain oxidations and the products of liquid-phase cyclohexane oxidation. Discussions focus on the applicability of the stationary state method to liquid-phase oxidation.

Problems of the involvement of molecular complexes of oxygen with variable-valence metal compounds in the liquid-phase oxidation of organic compounds, including the chain initiation reactions in radical chain oxidation, via the interaction of such complexes with the hydrocarbon are considered.

In addition, the liquid-phase reactions are well applicable for the oxidation of various olefins and BD because of high reactivity of these hydrocarbons that allows the oxidation at low.

Abstract: The CeO2 nanorods (CeNR) promote the oxidation of ethylbenzene (PhEt) and cyclohexene with t-BuOOH, at temperatures as low as 55 ºC.

For both substrates the saturated C-H bonds are preferentially activated over the unsaturated ones. The catalyst seems fairly stable towards leaching phenomena. The liquid-phase oxidation catalysis may. THE LIQUID PHASE OXIDATION OF HYDROCARBONS Being an account of the work carried out at the Science Laboratories, Durham University (Durham Division) and the Dyson-Perrin Laboratories, Oxford University during the period under the direction of W.A.

Waters, M.A., Sc.D., Ph.D., F.R.I.C. Phoenix Equipment has several liquid phase oxidation units for removing H2S from Gas Streams. Below is a link to our refinery units where you can find several oxidation processes and other refinery units as well as a well-written piece by Gary Nagl called, “The State of Liquid.

Ruthenium‐Catalyzed Oxidation of Alkenes, Alcohols, Amines, Amides, β‐Lactams, Phenols, and Hydrocarbons (Pages: ) Shun‐Ichi Murahashi Naruyoshi Komiya. Liquid-Phase Oxidation of Hydrocarbons.

Nikolai Markovich Emanuel, Evgenii Timofeevich Denisov, and Zinaida Kushelevna Maizus. Translated from the Russian edition (Moscow, ) by B. Hazzard. Plenum Press, New York, pp., illus. The essence of the inventive non-barbotage oxidation process is ensuring that the oxidizing agent delivered to the process reactor undergoes continued contact only with exposed surfaces of the liquid phase of the hydrocarbons being oxidized configured as at least one of: formed liquid phase thin film(s), liquid phase continuous stream(s), and.Liquid-phase aerobic oxidation of hydrocarbons naphthenic-paraffinic concentrate.

С of Azerbaijan oils blend diesel fraction in the presence of pentanuclear complexes of Cr, Co, Ni. and their mixtures. with Zn, Cr salts of natural petroleum acids (MeNPA) has been conducted.Partial oxidation of acetaldehyde by oxygen in the liquid phase was studied in the temperature range from −10 °C to 34 °C, oxygen flow rate from 90 .

39765 views Tuesday, November 24, 2020